腐植酸对土壤重金属镉的淋溶效果及吸附解吸机制研究.pdfVIP

研究论文 腐植酸 2015 年第1期 腐植酸对土壤重金属镉的淋溶效果及吸附解吸机制研究 * 单瑞娟 黄占斌 柯 超 章智明 田 野 (中国矿业大学(北京)化学与环境工程学院 北京 100083) 摘 要：为了揭示腐植酸对土壤重金属镉(Cd)的淋溶效果及吸附解吸机制，本研究采用土柱模拟淋溶方法和吸附 解吸试验方法，开展不同腐植酸用量对土壤重金属Cd的淋溶试验，以及pH变化对土壤Cd吸附解吸效应。结果表 明，不同腐植酸用量导致土壤淋溶液中Cd含量有别，淋溶液中Cd含量并不随土壤腐植酸用量的增加而减少，而 是当腐植酸的用量达到一定浓度时，淋溶液中Cd含量减少趋稳。在酸性条件下，各处理腐植酸对Cd的吸附性 显著；在碱性条件下，当pH=11时，各处理土壤对Cd的吸附量达到最大且基本稳定。解吸试验显示，随着pH增 加，各处理的解吸量不断减小，当pH=11时，各处理土壤对Cd的解吸量最小，处理间差异不显著。 关键词：重金属镉(Cd) 腐植酸 pH 淋溶 吸附-解吸 中图分类号：TQ314.1 文献标识码：A 文章编号：1671-9212(2015)01-0012-06 Study on Humic Acid for Leaching Effect of Cadmium in Soil and Its Adsorption-Desorption Mechanism Shan Ruijuan, Huang Zhanbin*, Ke Chao, Zhang Zhiming, Tian Ye (School of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing, 100083) Abstract: In order to investigate the remediation of humic acid on heavy metal cadmium (Cd) in soil, simulation ex- periment of soil column leaching and adsorption-desorption method were used in terms of different dosages of humic acid and the effects on adsorption-desorption were demonstrated under different soil pH value. The results showed that different dosage of humic acid could lead different amount of Cd in leaching solution and the amount of Cd did not decrease with increasing of the dosage of humic acid. However, when the dosage of humic acid reached certain con- centration, Cd in the solution reduced to the stable trend. Under acid conditions, the humic acid adsorption quantities of experimental treatments were significant. Under alkaline c