介孔氧化铝及其前体的晶体结构与表面化学的研究进展.pdfVIP

2010 39 7 PETROCHEM ICA L TECHNOLOGY 809 关丽丽, 柳云骐, 李广慈, 刘晨光 (( ) CNPC , 266555) [] , () , [] ; ; ; [] 1000- 8144 ( 2010) 07 - 0809- 09 [ ] TQ 133. 1 [] A R esearch Progress in C rystal S tructure and Surfa ce Chem istry of M esoporous A lum ina and Its P recurso r Guan Lili, Liu Yunqi, L iGuan ci, Liu Chen uan ( State K ey L aboratory of H eavy O il, Key Laboratory o f C atalysis, CN PC, Ch ina U n iversity of Petro leum ( East Ch in a) , Q in dao Shandon 266555, Ch ina) [ Abstract] R esearch pro resses in crystal structure and surface chem istry ofm esoporous alum ina and its precursor w ere rev iew ed. S tartin from the m ain synthetic routes of m esoporous alum ina, its con trolled synthesis w as sy stem ically summarized. In addition, new varieties of m esoporous alum ina w ith ordered pores d ifferen tm orpholo ies and nanocry stalline alum ina assemblies w ere in troduced in detail. The crystal row th and contro l strate ies, and the surface alum inum m icroenvironmen t and the surface hydroxy l roups w ere discussed in detai.l Hot issues and research opportunities in th is field w ere prospected, and the su estion of stren then in research in the alum inam esolevelw as proposed. [ K eywords] m esoporous alum ina; m esoporous alum ina precursor; cry stal structure; surface chem istry A 1 O , , 2 3 , , , 9 ( - , - , - , !- , ∀- , #- , , ∃- , %- , - A 1 O ) , 2 3 , ( - A 1 O % -