LIX84和LIX54混合萃取剂从氨性溶液中萃取锌的研究.pdf

第 42 卷第 3 期 中南大学学报( 自然科学版) Vol.42 No.3 2011 年 3 月 Journal of Central South University (Science and Technology) Mar. 2011 LIX84 和LIX54 混合萃取剂从氨性溶液中萃取锌的研究 吴贤文，尹周澜，刘春轩，胡慧萍，丁治英，陈启元 ( 中南大学 化学化工学院，湖南 长沙，410083) 2+ − 摘要：以 Zn -NH -Cl -H O 氨性溶液为水相，考察 LIX84 和 LIX54 混合萃取剂相对含量、相比、被萃水相中锌 3 2 离子浓度、总氨浓度和 pH 对锌萃取率的影响。借助计算软件 GEM-Selektor 从理论上分析被萃水相 pH 对锌萃取 率的影响。研究结果表明：相比、被萃水相总氨浓度和 pH 是影响锌萃取率的主要因素；被萃水相是总氨浓度为 3 mol/L、锌离子质量浓度为 3 g/L 的氨性溶液，当NH 与 NH Cl 的物质的量比n(NH ):n(NH Cl)为 3、相比为 1:1 3 4 3 4 时，于40 ℃振荡 30min，单次锌萃取率可达 76.42% 。 关键词：氨性溶液；萃取剂；萃取；锌 中图分类号：TF813 文献标志码：A 文章编号：1672−7207(2011)03−0605−05 Zinc extraction from ammoniacal solutions with mixture of LIX84 and LIX54 WU Xian-wen, YIN Zhou-lan, LIU Chun-xuan, HU Hui-ping, DING Zhi-ying, CHEN Qi-yuan (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) 2+ − Abstract: With Zn -NH -Cl -H O solution as ammoniacal solution, the effect of such factors as the relative content of 3 2 the mixed extractant, phase ratio, concentration of zinc ion, total ammonia concentration and pH in the aqueous solution on zinc extraction ratio was studied. The effect of pH on zinc extraction ratio was theoretically illustrated with CEM-Selektor software. The experimental results show that phase ratio, total ammonia concentration and pH are the main factors influencing the zinc extraction r