聚乙烯亚胺_纤维素的合成及表征.pdfVIP

37 8 Vol. 37 No. 8 2009 8 JOURNAL OF NORTHEAST FORESTRY UN IVERSITY Aug. 2009 /1) 李宏振 方桂珍 李俊业 马英梅 艾 青 张 锐 马艳丽 ( (), , 1 0040) 以聚乙烯亚胺 (PE I)为功能基团, 以微晶纤维素(M CC) 为载体, 通过环氧氯丙烷将聚乙烯亚胺接枝 到纤维素上, 制 高分子材料聚乙烯亚胺 /纤维素( PE I/MCC)考查了各影响因素对 PEI/MCC制备的影响, 通过 红外光谱分析X 射线衍射分析元素分析和 SEM 对 PE I/MCC 的结构进行表征, 探讨了反应机理实验结果表明 PE I/MCC 的合成条件为:在 N 保护下, m (环氧化纤维素( EC) ) m ( PE I) = 16, 反应介质为 pH = 11的氢氧化钠水 2 溶液 40 mL, 反应温度为 70 , 反应时间为 12 h过滤产物, 用水洗涤至中性, 40 真空干燥 24 h, 微黄色固体, 即为 PEI/MCC其氮的质量分数为 . 27% , 结晶度为 78. 36% , 产物的结晶结构和表面结构已经发生了改变 微晶纤维素; 聚乙烯亚胺; 合成; 材料 TQ3 2. 79 P reparation and Character ization of P oly ethylene im ine / Cellu lose /L iH ongzhen, FangGuizhen, Li Junye, MA Y ingme,i Ai Q ing, Zhang Rui, Ma Yan li(Key Laboratory of B io-based Material Science and Technology, M in istry of Education ( Northeast Forestry University), H arb in 1 0040, P. R. China) / / Journal of Northeast ForestryUniversity. - 2009, 37( 8). - 71~ 73 A new type of polymerm aterial of polyethylenemi ine/cellulose ( PE I/MCC) was syn thesized w ith PE I as functional group and mod ified cellu lose as carrier. PEIw as grafted on cellulose by us ing epoxy ch loropropane. PE I/MCC w as charac- terized by XRD, FT-IR, elem ent analyzer, and SEM. The m echan ism of reaction was d iscussed. The synthesis procedure w as obtained as mass ratio of epoxycellu lose to PE I 16, pH 11, sodium hydroxide solution 40 mL, tem perature 70 degrees C, and reaction tmi e 12 hours under nitrogen atmosphere. The productw as filtered and bathed to pH 7 byw ater, and then w as put into the vacuum cham ber drying at 40 degrees for over 24 hours. A k ind ofw hite-to-brown solid m aterialw as ob- tained, w ith nitrogen conten t of . 27 percent and crystallin ity degre