探讨3间甲苯氧基1,2环氧丙烷的合成.pdfVIP

3--1,2- 1 ?? -[1~3] ???C-O C-S C-N C-C σ[4] NaOH KOH K2CO3 [5~7] Pchelka BK[8] [9] 2 2.1 C7H8O C3H5OCl C19H42NBr C13H22NCl NaOHNa2SO4 C7H8C4H10O NICOLET AVATAR 330FT-IR KBr ZF-184-1 2.2 3- 3- -1,2- 2.3 SN2 E2 () ArO-C-Cl ArO- 2.4. 2.3 g 0.057 mol 100mL 20 mL 5 mL 0.048 mol 40 min 0.5g 30 min 11.7 mL 0.150 mol 5h 3 3.1 C-H 2999 cm-1 2924 cm- 1 2834 cm- 1 C-H 1602 cm- 1 1585 cm- 1 1490 cm- 11453 cm- 1 1362 cm- 1 -CH3 1262 cm-11160 cm-1 C-O 909 860 cm-1 3.2 2:1 3:14:1 5:16:1