高性能纤维热降解行为及动力学参数比较刘晓艳.pdfVIP

33 2 ( ) Vol. 33, No. 2 2007 4 JOURNAL OF DONGHUA UNIVERSITY Apr. 2007 : 67 - 0444(2007) 02- 020 - 06 * 刘晓艳 , 于伟东, 2 ( . , 20005 ; 2. , 430073) Ó Ó Ó : 利用T G 方法研究3种高性能纤维材料( Zylon ( PBO) , Kevlar 29 和Kermel 纤维) 在氮气和空气中的热 降解过程和动力学参数. 验发现, 样品在氮气中的降解特征温度比空气中的高30 e 左右, 且PBO 纤维热降解的特征 温度最高, 所建立的综合温度指标可有效评价这一特性. 同时, 利用Freeman-Carroll 法研究样品的热降解动力学参数, 计算比较3种材料的反应活化能及反应级数, 结果与特征温度分析基本一致. : 高性能纤维; 热降解; 热失重; 活化能 : T Q 342. 7 : A Thermal Degradat ion Behavior and Kinet ics Parameters of High Performance Fibres L I UX iao-y an , YU Wei-d ong , 2 (1. Collegeof Textiles, DonghuaUniversity, Shanghai 200051, China; 2. Collegeof TextilesandMaterials, uhanInstituteofScienceandTechnology, uhanHubei 430073, China) Abstract: T he thermal degradation and kinetics parameters of three types of high performance fibers ( HPFs) are measured by the thermogravimetric analysis (T G) under nitrogen and air atmosphere, w hich Ó Ó are Kevlar 29, Kermel and PBO fibres. T he degree of degradation and the characteristic degradation temperatures are obtained from both of the TG and DT G curves. T he degradation temperatures in nitrogen are higher than those in air about 30 e , and the PBO fibre has the highest thermal degradation temperature w hether in air or nitrogen atmosphere. The complex index of temperature Tc proposed can be used to evaluate the thermal stability of