PCL_PVP共混膜的制备与性能研究.pdfVIP

第 25 卷 第 2 期 五邑大学学报（自然科学版） Vol.25 No.2 2011 年 5 月 JOURNAL OF WUYI UNIVERSITY (Natural Science Edition) May 2011 文章编号： 1006-7302 （2011 ）02-0043-04 1 PCL/PVP 共混膜的制备与性能研究 陈向标 （五邑大学 纺织服装学院，广东 江门 529020 ） 摘要：利用溶液浇铸法制备了聚己内酯（PCL ）/ 聚乙烯基吡咯烷酮(PVP)共混物膜，通过测试 膜的表面接触角、吸水率，研究了共混膜的亲水性能；通过测试膜的断裂伸长率和断裂强度， 研究了共混膜的力学性能；用 XRD 对膜进行表征，研究了共混膜的结构 . 结果表明：PVP 的 加入对 PCL 的结晶度有一定影响；随着 PVP 质量分数的增加，水在 PCL/PVP 膜的表面接触角 逐渐减小，吸水率逐渐增大；适当比例的 PVP 含量有助于增强 PCL 的力学性能. 关键词： 聚己内酯；聚乙烯基吡咯烷酮；共混膜；溶液浇铸法 中图分类号：TS101.92+ 3 文献标志码：A A Study of Preparation of PCL/PVP Blend Films and Their Properties CHEN Xiang-biao (College of Textile Clothing, Wuyi University, Jiangmen 529020, China) Abstract: Polycaprolactone (PCL)/Polyvinylpyrrolidone (PVP) blend films were prepared by using the solvent casting method. Then the hydrophobic properties of the blends was studied by testing the surface contact angle and water absorption of the films; the mechanical properties of the blends was studied by testing the films ’ breaking strength and elongatio n at break; and the structure of the blend was studied by characterizing the films with XRD. The results showed that: the addition of PVP has some influence on the crystallinity of PCL. With the increase of PVP concentration, the contact angle of water on the PCL/PVP film surface decreased, while the water absorption increas ed; appropriate proportion of the PVP content helps to streng