GC-MS法的研究环维黄杨星D中有关生物碱.pdfVIP

GC．MS法研究环维黄杨星D中有关生物碱 郛青’2’，吕霞。，谭力2fI中田药科大学．江苏南京210009：2．．江苏省食品药品检验所．江苏南京210008) 摘要：目的 突破性并创新性研究环维黄杨星D中有关生物碱．方法 采用GC．MS法，HP．5弹性毛细管色谱柱分离，升 进样口温度下所得到的色谱图及纯度有较大差异，280℃气化时色谱峰可出现23个．结论GC．MS法能有效分离并确认或 推测环维黄杨星D中有关生物碱，但出峰受进样口温度影响． 关键词：环维黄杨星D；有关生物碱：GC·MS in D GC—MS towaredstheRelatedAlkaloids Study Cyclovirobuxine 210008) Control，Nanjing To further intherelatedalkaloidsin D method． ABSTRACT：OBJECnVEmake innovative progress cyclovirobuxineusing METHODSGC．MSmethodwas introducedinthe iP·5 columnwasusedto thealkaloids．oven newly stud，，l capillary separate from140℃to285℃atarateof were ati60C～280℃inmode． temperature 20℃／min,thesample programmed injected splitless aconstant as amountwas allinstances．transferIineWassetto290℃．Elwas flowrof1．0mL·rain—N2 1此for using c：arriel．injection as with scan 450)m／zscanrateof selectedionSOUre,eelectron 70e．source wasat230℃．fullfiom(50to with energ)’of temperamre Das 1000rn／s．RESULTSTherelatedalkaloid variedincvclovirobuxinemanufacturediffered．the composition chromatograph carl variedasinlet was theinletwasat chould 23． temperature changed,when 280C，thepeaks partly greatly appear CONCLUSlONGC·MSmethodcan and or therelatedalkaloidsin D．but separateidentify eyciovirobuxine effectively speculate the were inlet p