铜铝钎焊用Zn-Al钎料的电化学腐蚀性能研究.pdfVIP

（2）有色金属材料 铜铝钎焊用Zn-Al 钎料的电化学腐蚀性能的研究 王凯，刘正林，杨凯珍 （广州有色金属研究院，广东广州510650） 摘 要：使用高频感应炉通过铸锭冶金法制备了铜/铝钎焊用Zn-Al 钎料，通过浸泡腐蚀试验、电化学腐蚀 实验对添加 Mg 元素的钎料的耐蚀性能进行了评价分析，并探讨了其腐蚀机理。研究结果表明，添加 Mg 元素可显著提高钎料基体的电极电位，从而显著提高钎料本身的耐腐蚀性能，并不会显著降低铜铝接头的 强度。加入Mg 元素的Zn-Al 钎料，配合CsF-AlF 3 无腐蚀中温钎剂，采用高频感应加热钎焊连接铜铝管， 通过浸泡腐蚀试验后，仍可获得高剪切强度的接头。 关键词：铝铜钎焊；Zn-Al 钎料；电化学腐蚀；阳极极化 Research of electrochemical corrosive characteristics of Zn-Al solders for Al/Cu Brazing WANG Kai，LIU Zhenglin ，YANG Kaizhen (Guangzhou Research Institute of Non-ferrous Metals ，Guangzhou 510650) Abstract：This paper presents a fast arc detection method which is used for scanned line-drawing graphics recognition. It is a kind of method which is from arc supposition to arc verification. Firstly extract the skeleton of the line-drawing image, then use the piecewise linear polygon to approximate the skeleton for more simplification and reducing the quantum of data. After that, the local discrete curvature of every dominant point of the linear polygon is calculated and the discrete curvature is used to assume some arcs exist locally. Finally the hypotheses are verified by mapping the hypothetical arcs’back into the original image according to the arcs ’circle parameters. This proposed method has the advantages that it can deal with the conditions of rupture, intersection and overlapping and it is robust and fast. Key words ：Al/Cu brazing; Zn-Al solders; electrochemical corrosion ；anodic polarization 0 引言 铜管大量应用在制冷行业中，但由于铜的市场价格较高，为降低生产成本， 用价格较低的铝代替铜已成为制冷行业中的普遍做法。由于在一些制冷管路构件 （如干燥过滤器、毛细管等）中，铜管还没有替代材料，因此铝管和铜管间的连 接成为了一个关键工艺问题。传统的铝、铜管焊接多采用储能焊和摩擦焊方法， 但在制冷行业中，冷凝连接管壁厚只有 0.6～1.0mm，采用传统方法工艺复杂且 [1] [2] 焊缝渗漏概率高 。目前最理想的解决方法是钎焊连接 。钎焊连接可获得较高