NR_SBR并用磁敏橡胶材料的制备及性能.pdf

工艺·技术·应用 NR/SBR 并用磁敏橡胶材料的制备及性能 虞耀君，陈先忠 （九江学院机械与材料工程学院，江西九江 332005 ） 摘 要：以偶联剂 KH-570 改性羰基铁粉，用湿法工艺制备了综合性能较好的实用型磁敏橡胶，研究了羰 基铁粉含量对天然橡胶/丁苯橡胶（NR/SBR ）并用橡胶基磁敏橡胶的性能影响；同时利用扫描电镜观测改性羰 基铁粉表面和磁敏橡胶复合材料断面的微观结构。结果表明，通过偶联剂改性的羰基铁粉其晶体结构未发生变 化，且表面有一层致密的包覆层；以 NR/SBR 并用橡胶为基体的磁敏橡胶，当羰基铁粉含量为 300 质量分数时， 可表现出较好的机械性能与磁流变效应。 关键词：磁敏橡胶；机械性能；磁流变效应；并用橡胶 中图分类号：TQ330.1 文献标识码：B 文章编号：1001-3830(2010)03-0046-04 Preparation and Performance of Magnetorheological Elastomer Based on NR/SBR Rubber YU Yao-jun ，CHEN Xian-zhong School of Mechanical Materials Engineering, Jiujiang University, Jiujiang 332005, China Abstract ：Practical magnetorheological elastomers(MRE) based on NR/SBR rubber with better properties were prepared by wet method using KH-570-modified carbonyl iron powder(CIP) , and the influences of CIP content were investigated on the MRE performances.The carbonyl iron powder was analysed by X-ray powder diffraction (XRD) and the cross-section of MRE was characterized by scanning electron microscopy(SEM). The results indicated that the structure of modified CIP was not changed and the particle surface of CIP was densely covered with coupling agents. Optimum mechanical properties and magnetorheological effect of MRE based on NR ／SBR rubber was obtained for sample with content of carbonyl iron powder of 300. Key words ：magnetorheological rubber ； mechanical properties ； magnetorheological effect ； mixing of rubber 要集中在磁流变液及其应用方面，自 2002 年起才 1 引言 有磁流变弹性体的研究论文发表[3~7] 。中国科学技 磁敏橡胶是磁流变材料的一个分支，也可称为 术大学对磁流变弹性体的剪切性能进行了实验研 磁流变弹性体，是一种其流变性能可由外加磁场控 究[6]，研制了一种磁流变弹性体，并建立了一套测 制的新型功能材料