TiO2薄膜的制备及其电致变色性能.pdfVIP

TiO。薄膜的制备及其电致变色性能／牛微等 · 17· TiO：薄膜的制备及其电致变色性能。 牛微1一，王 刚1，刘旭东1，毕孝国1，孙旭东2 (1 沈阳工程学院能源与动力学院，沈阳110136；2东北大学材料与冶金学院，沈阳110819) 摘要 表征了薄膜的结构和热重特性，使用电化学工作站和紫外一可见分光光度计研究了TiO：薄膜的电致变色性能。结果 表明，外加电压控制在±2V、热处理温度为250℃时，Ti02薄膜为不定形结构，具有较好的电致变色特性，注入电荷 密度为5．13mC·cm～，循环可逆性K值为0．49，着色态透光率在60％以下，着色态、褪色态光谱透过率相差20％。 关键词TiOz薄膜电致变色溶胶一凝胶热处理 中图分类号：TB34 文献标识码：A and Performanceof ThinFilm Electrochromic TiOz Preparation NIUWeil”，WANG Xiaogu01，SUNXudon92 Gan91，LIUXudon91，BI of Schoolof (1Schoolof and Institute 110136；2 EnergyPower，ShenyangEngineering，Shenyang Northeastern 110819) University，Shenyang films methodsonITOconductivesubstratesurface．Structural AbstractTi02 were by glass preparedsol-gel and were XRDandTG-DTA，eleetrochromicwere thermogravimetriepropertiesinvestigatedby propertiesinvestigated visible indicatethe filmshave electrochemicalworkstationandultraviolet results that TiOz better by spectroscopy．The whenthefilm withheattreatment at250℃and electrochromic are properties amorphous temperature appliedvoltage of±2Vwith tothereferenceelectrode．And is5．13 K density mC·cm～．cyclic respect injectedcharge reversibility valueis0．49，transmittanceisbelow60％andthedifferenceoftransmittancebetween