Rheology in Cosmetics课件.pptVIP

Rheology in Cosmetics 剪切率 (Shear Rate) 剪切率SHEAR RATE RANGE PRACTICAL APPLICATIONS 触变性(thixotropic)和震凝性(rheopectic) 指在等温条件下,某些液体的流动粘度随外力作用时间的长短发生变化的性质。粘度变小的称触变性,变大的称震凝性,或称反触变性。 THIXOTROPY - structure present in a sample which takes time to rebuild after it has been sheared 屈服点，使流体开始流动所需的最小切应力 YIELD POINT - the stress which needs to be placed on a material in order for the sample to flow 评价屈服“点”/屈服“应力” : 方法1(CSR 模式 / 单独使用或通过 SST s/w): 应力增加 牛顿型流体(Newtonian fluid)剪应力与速度梯度的关系完全符合牛顿粘性定律的流体.NEWTONIAN FLUID - a fluid that does not change viscosity with change in shear rate 非牛顿型流体-假塑性(non-Newtonian -Pseudoplastic fluid )-粘度随剪切率升高而减小Performance of the Pseudoplastic fluid material which displays a decrease in viscosity with increasing shear rate 非牛顿流体-塑性(non-Newtonian -Plastic fluid ) 塑性流体表现为粘度随剪切率升高而减小，有屈 服值(剪切变稀) Performance of the Plastic fluid material which displays a decrease in viscosity with increasing shear rate; this type of material also exhibits a yield point; these materials are shear-thinning 非牛顿流体-胀性 (non-Newtonian - Dilatant fluid ) 胀性流体表现为粘度随剪切率升高而增大Performance of the Dilatant fluid material which exhibits an increase in viscosity as shear rate increases 二、流变学中有关粘度 ,Viscosity -典型液体的大概粘度值 (Pa s) 通过比较触变曲线/屈服数据等进行配方改进和QC 测试。 MORE ADVANCED TEST METHOD 谢谢! Thank you! * * 化妆品中的流变学 LIN GANG  Estée Lauder Companies Innovation Institute (China) 牛顿将粘度定义为所加应力与流动梯度的比例。 Stationary Plate Moveable Plate A=Area cm2 A=Area cm2 X = Distance F = Force (dynes) 剪切力（Shear Stress） 粘度 *假定: 板的长度远大于板的间距。 一、流变学介绍 定义I Rheology introduction I 漆刷的速度 Estimate the velocity of the paint brush = 50 cm/sec 油漆的厚度 Estimate the thickness of the layer of paint being applied = y = 0.01 cm 剪切率计算Calculate shear rate = 50 cm/sec 0.01cm = 5,000 sec-1 Example: 刷油漆 Shear rate of applying paint with a brush: v y 一、流变学介绍 定义I Rheology introduction I 一、流变学介绍 定义II Rheology introduction II Strain Stress Yield Stress Yield Strain modulus 方法2 (CSS 模式/ 通过 Rheo 2000 s