《ArylguanidinePdcatalyzed Suzuki Crosscoupling Reaction at Room Temperature》.pdfVIP

CHEM．I砸S．CHINESEI刷nⅢRSlllES201 2，28(2)，242—244 Suzuki Aryl—guanidine／Pd—catalyzedCross—coupling ReactionatRoom Temperature LI DUAN Yan．chunl，LIN Suo-b02，LI Ying-jiel，ZHANGSheng-hai2’andHai．fen91‘ l 300l 2，P．R．Chi眦： 1．De泌rtem可Org口mcChemis呻，college可Chemis呻，Jil{nUn如ers渺，Chd豫chn 2．KeyL曲omtow西Polymer l瑚titule可Appliedchemis晒， Ecomnleriats，C}lnngchHn Chinese l Chin口 30022，P．R Acndemy彰Sciences，Chnngchn AbstractFour usedfornle a哆l-gu卸idines(AG)weres”thesized锄d palladium-cataIyzedSuzu“cross—coupling to acid reactiontestthecatalnicactivity．InmepresenceofsterjcbulkAG，whenarylbromide锄darylboronicwere usedaSttIe SuzukireactioncouIdbecarriedout atroom in solventto react醐ts，the smoothIy tempera_turcaqueous in waS for an．0rdthe alsosuccess向ItIle ofactivated higtlyield．Thiscatalysissystem cross—couplingproduct coupJing chloridesatroOm aryl temperamre． KeywordsAryI-霉Ⅳanidine：Suzukircaction；Palladi啪；Ligand AnicIeID1005．9040(2012)-02-242-03