NiCo氧化物制备.pdfVIP

Materials Letters 58 (2004) 1415– 1418 /locate/matlet Effect of precipitant on preparation of Ni–Co spinel oxide by coprecipitation method Chi Bo *, Jian-Bao Li, Yong-Sheng Han, Jin-Hui Dai State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, PR China Received 14 July 2003; accepted 29 September 2003 Abstract Ni–Co spinel oxide was synthesized via the coprecipitation method. Hydroxide, carbonate, and oxalic acid were used as precipitants in order to compare their effect on the physicochemical properties and electrocatalytic properties of oxide. The result shows that hydroxide coprecipitation method can prepare Ni–Co spinel oxide with specific surface area of 67.19 m2/g, and the oxide has the best electrocatalytic behaviors in contrast to the oxide prepared by the other two precipitants. D 2003 Elsevier B.V. All rights reserved. Keywords: Ni– Co oxide; Precipitant; Coprecipitation; Powder technology; Catalysts 1. Introduction 2. Experiment Cobalt-based spinel oxide NiCo O is stable and active Co(NO ) 6H O and Ni(NO ) 6H O were dissolved in 2 4 3 2 2 3 2 2 in alkaline solution and is more available and cheaper than distilled water in the molar proportion of 2:1. The precipitant noble metals (as Pt, Ru, etc.) in many anodic processes, such