掺杂铕氧化铋光催化剂的制备及其可见光的光催化性能.pdfVIP

10.7694/jdxblx 掺杂铕氧化铋光催化剂的制备 及其可见光的光催化性能 刘卓婧 宫喜君 张凤君 吕聪 赵 静 吉林大学地下水资源与环境教育部重点实验室，环境与资源学院，长春130012 摘要：通过在Bi2O3中掺杂稀土元素Eu，以甲基橙为目标污染物，考察稀土掺杂比、离子液 体浓度、灼烧温度、灼烧时间和催化剂投加量对光催化效果的影响，并利用X射线衍射 (XRD)和紫外-可见漫反射光谱(UV-VisDRS)研究样品结构.结果表明：最佳制备条件为 n(Eu)：n(Bi)=0.25，离子液体浓度为0.0025mol/L，灼烧温度为400℃，灼烧时间为5h， 最佳投加量为5.0g/L;在最佳制备条件下制得的光催化剂在可见光光源下对甲基橙的降解 率为92.57％，远高于未掺杂Eu光催化剂的降解率(29.26％)；制备的催化剂为四方晶系，吸 收边带红移约120nm，禁带宽度由2.86eV变为2.37eV.即掺杂Eu可扩展光的响应范围， 提高Bi2O3的光催化活性. 光催化；氧化铋；可见光；铕掺杂 X703.1;TB39 A 1671-5489(2013)03-0538-07 PreparationandVisible-LightPhotocatalyticPerformanceof EuropiumDopedBismuthOxidePhotocatalyst LIUZhuo-jingGONGXi-junZHANGFeng-junL(U)CongZHAOJing KeyLabofGroundwaterResourcesandEnvironmentofMinistryofEducation, CollegeofEnvironmentandResources,JilinUniversity,Changchun130012,China Abstract:Europium(oneoftherareearthelement)wasdopedintoBi2O3toextendthelightresponse scopeofbismuthoxidephotocatalystandtheeffectsofeuropium-to-bismuthratio,concentrationof ionicliquid,calcinationtemperature,calcinationtimeanddosageofthecatalystonthephotocatalytic activityofeuropiumdopedbismuthoxidewereinvestigated.Methylorangewasusedasthetarget pollutant.Theoptimumpreparationconditionsareeuropium-to-bismuthratio(n(Eu):n(Bi))is 0.25,concentrationofionicliquidis0.0025mol/L,calcinationtemperatureis400℃ andcalcination timeis5h.Theoptimumdosageofthecatalystis5.0g/L.Furthermore,thepreparedsampleunder optimumconditionshaswellphotocatalyticactivityundervisiblelightwherethedegradationrateof methylorangeisupto92.57％.Butthedegradationrateofmethyorangewasonly29.26％ whenit wasdegradedbynon-dopedphotocatalyst. ThepreparedsampleswerecharacterizedbyX-ra