分子间磷杂菲与磷腈双基协同阻燃环氧树脂研究.pdfVIP

第 4 1 卷 ，第 7 期 工 程 塑 料 应 用 Vol.4 1，No.7 4 2013 年 7 月 ENGINEERING PLASTICS APPLICATION Jul. 2013 doi:10.3969/j.issn.1001-3539.2013.07.001 分子间磷杂菲与磷腈双基协同阻燃环氧树脂研究* 钱立军，孙楠，许国志 ( 北京工商大学材料科学与工程系 ，北京 100048) 摘要：将六苯氧基环三磷腈(HPCP) 和9 ，10– 二氢–9– 氧杂– 10– 磷杂菲– 10– 氧化物(DOPO) 复合应用于阻燃 环氧树脂(EP) ，通过极限氧指数和垂直燃烧性能测试、热失重分析、锥形量热分析等研究了其协同阻燃EP 的性能，探 讨了协同阻燃机理。结果表明，当DOPO 在HPCP ／DOPO 复合阻燃剂中所占比例达到80% 时，样品的阻燃级别达 到UL94 V–0 级，总热释放量降低，优于两种阻燃剂单独使用条件下对EP 的阻燃效果，表明磷腈和磷杂菲两种阻燃 剂之间存在着协同阻燃效应。 关键词：磷腈；磷杂菲；环氧树脂；协同阻燃 中图分类号：TQ323.5 ，O633.13 文献标识码：A 文章编号：1001-3539(2013)07-0004-04 Flame Retardant Synergistic Effect of Intermolecular Phosphaphenanthrene and Phosphazene Groups on Epoxy Resin Qian Lijun ，Sun Nan ，Xu Guozhi (Department of Materials Science Engineering ，Beij ing Technology and Business University ，Beij ing 100048 ，China) Abstract ：The non-halogen flame retardants hexa-phenoxycyclophosphazene(HPCP) and 9 ，10-dihydro-9-oxa- 10- phosphaphenanthrene-10-oxide(DOPO) commonly incorporated into epoxy resins.The properties of flame retardant epoxy resins were studied by the limited oxygen index ，UL94 vertical burning ，thermo gravimetric analysis and cone calorimeter.The flame retardant synergistic mechanism was also discussed.The results show that when the loadings of DOPO in the DOPO ／HPCP mixture is 80% ，the flame retardant rating of epoxy resin thermoset can reach UL94 V–0 and the total heat release is reduced.The flame retardant properties are better than that of the samples with HPCP and DOPO separately.It means that the flame retardant synergistic effect between HPCP and DOPO is existent. Keywords ：phosphazene ；DOPO ；epoxy resin ；