英硅酸盐玻璃的结构.pdfVIP

The structure of sodium silicate glass Chengde Huang and A. N. Cormack Centerfor Glass Research, New York State College of Ceramics, Alfred University, Alfred, New York 14802 (Received 15 August 1990; accepted 31 August 1990) Atomistic scale computer simulations can provide a more detailed understanding of the structure of glasses. Our results on sodium silicate glasses show that sodium ions are associated with nonbridging oxygens and that the sodium ions and nonbridging oxygens tend to aggregate to form silica rich regions and alkali rich regions. Interatomic distances of our simulated glasses are in good agreement with experimental results. O-Si-O bond angles are centered 0 0 around 109 with narrow distributions. Si-O-Si bond angles are broadly distributed from 120 to 180·with an average of about 153°. I. INTRODUCTION from crystalline solids to glasses. We will demonstrate that molecular dynamic computer simulations with improved in- There have been a number of experimental structural studies of silicate glasses. The most striking information ob- teratomic potentials can help us understand glass structures in more detail. In this paper, we will concentrate on our tained concerning the structure of glass has been that ex- tracted from radial distribution functions. The cl