2007高分子专业英语试题.docVIP

一、将下列英语片段翻译成汉语 Abstract Hyperbranched poly(2-((bromobutyryl)oxy)ethyl acrylate) (HPBBEA) was grafted onto the exterior surface of mesoporous silica nanoparticles (MSNs) by surface-initiated self-condensing atom transfer radical vinyl polymerization (SCATRVP). The MSNs with ATRP initiator anchored on the exterior surface (MSN-Br) were prepared by the reaction of 5,6-dihydroxyhexyl-functionalized MSNs (MSN-OH) with a-bromoisobutyryl bromide. Afterwards, MSN-Br was utilized as initiator in the SCATRVP of inimer BBEA, resulting in core–shell nanoparticles with MSN core and HPBBEA shell (MSN-g-HPBBEA). The molecular weight of HPBBEA increased with the increasing ratio of BBEA to MSN-Br. In view of the high density of bromoester groups on the surface of HPBBEA shell, MSN-HPBBEA was used to initiate the successive polymerization of (2-dimethylamino-ethylmethacrylate) (DMAEMA), forming core–shell nanoparticles MSN-g-HPBBEA-g-PDMAEMA. The resultant products were characterized by FT-IR, NMR, HRTEM and thermogravimetric analysis (TGA), etc. The pH-responsive property of MSN-g-HPBBEA-g-PDMAEMA was characterized by measuring the hydrodynamics radius at different pH values, and this core–shell nanostructure may have potential applications in biomedicine and biotechnology. Introduction Mesoporous silica nanoparticles (MSNs) have attracted considerable interest in recent years due to their unique characters, such as stable mesoporous structure, high surface area, large pore volume, tunable pore size and non-toxicity; they are ideal materials for hosting molecules [1–7]. However, some major restrictions have not been resolved yet; MSNs have faint solubility in most organic and aqueous solvents, and their compatibility with chemical and biological systems need to be improved. Once these limitations can be solved, MSNs could be utilized in broad ?elds, such as synthetic scaffolds to mimic enzymes, molecular vessels and materials for controlled drug delivery [8]. In order to enhance t