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LOGO Reporter: Xu Youfeng Professor: Wang Sheng Fe3O4@Carbon Microsphere Supported Ag ? Au Bimetallic Nanocrystals with the Enhanced Catalytic Activity and Selectivity for the Reduction of Nitroaromatic Compounds J. Phys. Chem. C 2012, 116, 22432 ? 22440 1、Synthesis of Fe 3 O 4 @Carbon Microspheres. 0.6 g of ferrocene 30 mL of acetone 3.0 mL of H2O2 was slowly added stirred for 30 min transferred to Te?on-lined stainless autoclave. The reaction was allowed to proceed for 24 h at 210 °C. collected by a magnet and washed with acetone for three times 2、Preparation of Fe 3 O 4 @C@Ag Microspheres. redispersed in ethanol for further use 5 mg of Fe 3 O 4 @carbon microspheres was dispersed using 15 mL of ethanol 20 mM of AgNO 3 and 20 μ L of n-butylamine the mixture was incubated for 50 min at 50 °C with vigorous shaking rinsed with ethanol and dried 3、 Preparation of Fe 3 O 4 @C@Ag ? Au Microspheres. 10 mg of Fe3O4@C@Ag microspheres dispersed in 20 mL of ethanol A certain amount of HAuCl4 incubated at 50 ° C for 1 h with vigorous shaking washed with the saturated NaCl solution and ethanol and dried in a vacuum oven. Scheme 1. Fabrication Schematic Diagram of the Fe 3 O 4 @C@Ag ? Au Composite Microspheres and the Reduced Protocol of 4-Nitrophenol by NaBH 4 Using Fe 3 O 4 @C@Ag ? Au Composite Microspheres as Catalyst Figure 1. TEM images of Fe 3 O 4 @carbon microspheres (a) and Fe 3 O 4 @C@Ag microspheres (b); FE SEM image of Fe 3 O 4 @C@Ag ? Au microspheres (c); EDX elemental line scanning pro ? les (d) corresponding to Fe (i), Ag (ii), and Au (iii), which are recorded along the line shown in the top inset of (d); PXRD patterns (e) of Fe 3 O 4 @carbon (i), Fe 3 O 4 @C@Ag (ii), and Fe 3 O 4 @C@Ag ? Au (iii); magnetic hysteresis curves (f) of Fe 3 O 4 @carbon (i), Fe 3 O 4 @C@Ag (ii), and Fe 3 O 4 @C@Ag ? Au (iii). Figure S1. EDX spectrum of Fe 3 O 4 @C@Ag-Au microspheres. Figure S2. XPS spectra of Fe 3 O 4 @C@Ag-Au microspheres (entry 3 in Table 1). Figure