锂离子电池用增强型凝胶聚合物电解质.pdfVIP

化 工 进 展 2009 年第28 卷第3 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·449 · 研究开发 锂离子电池用增强型凝胶聚合物电解质 1 2 2 胡拥军 ，陈白珍 ，陈 亚 1 2 （湖南城市学院化学与环境工程系，湖南 益阳 413000 ； 中南大学冶金科学与工程学院，湖南长沙 410083 ） 摘 要：用相转移法制备无纺布增强型聚偏氟乙烯-六氟丙烯聚合物电解质，用扫描电子显微镜和循环伏安对所制 聚合物膜性能进行表征，用充放电实验和交流阻抗测试聚合物电池的电化学性质。结果表明：无纺布增强后的聚 合物电解质电化学稳定窗口超过5.0 V，室温离子电导率达到2.3 mS/cm ，机械强度大幅度提高，以此制备的聚合 物电池阻抗降低，充放电时界面阻抗稳定，循环性能得以提高。 关键词：聚合物电解质; 锂离子电池; 相转移; 交流阻抗 中图分类号：TM 912 文献标识码：A 文章编号：1000 –6613 （2009 ）03 –0449 –04 Reinforced gel-polymer electrolyte for Li-ion batteries 1 2 2 HU Yongjun ，CHEN Baizhen ，CHEN Ya 1 2 ( Department of Chemistry，Hunan City University，Yiyang 413000 ，Hunan，China ；School of Metallurgical Science and Engineering，Central South University，Changsha 410083，Hunan ，China) Abstract ：Gel-polymer electrolyte based on poly(vinylidene) fluoride-hexafluoropropylene was prepared ，and reinforced by non-woven fabrics. Polymer membrane morphology and electrochemical properties were characterized with scanning electron microscopy and cyclic voltammogram，and the polymer batteries were studied by charge-discharge tests and A.C. impedance. Experimental results showed that the electrochemical stability window of reinforced polymer electrolyte reached 5.0V，its ionic conductivity at room temperature is 2.3 mS/cm. Non-woven fabrics not only reinforced the mechanical strength of polymer elect