含氟及非共平面结构可溶性聚酰亚胺的合成与性能研究.pdfVIP

4 梅 媚等：含氟及非共平面结构可溶性聚酰亚胺的合成与性能研究 绝缘材料 2015 ，48(6) 含氟及非共平面结构可溶性聚酰亚胺的 合成与性能研究 1 2 1 1 1 1 梅 媚 ，彭大伟 ，裴响林 ，刘婵娟 ，黄孝华 ，韦 春 （1. 桂林理工大学 广西有色金属及特色材料加工国家重点实验室培育基地 材料科学与工程学院， 广西 桂林 541004 ；2. 舟山市公安消防支队，浙江 舟山 316000） 摘要：采用4-氟苯甲醛和2-异丙基苯胺合成新型二胺单体双(4-氨基-3-异丙基苯基)-4-氟苯基) 甲烷(APFM) ，通 过“一步法”缩聚反应得到一类新型含氟及非共平面结构的可溶性聚酰亚胺，并对其结构与性能进行表征和分 析。结果表明：该聚酰亚胺呈现出良好的溶解性能、高耐热性、高光学透明性、低介电常数。 关键词：含氟聚酰亚胺；可溶性；热稳定性；光学透明性；介电常数 中图分类号：TM215 ；TQ323.7 文献标志码：A 文章编号：1009-9239（2015 ）06-0004-05 Study on Synthesis and Properties of Soluble Polyimides Containing Fluorine and Non-coplanar Structure 1 2 1 1 1 1 Mei Mei , Peng Dawei , Pei Xianglin , Liu Chanjuan , Huang Xiaohua , Wei Chun (1. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China; 2. Zhoushan City Fire Detachment, Zhoushan 316000, China) Abstract: A novel diamine monomer bis(4-amino-3-isopropylphenyl)-4-fluorophenylmethane was synthe- sized by 4-fluorobenzaldehyde and 2-isopropylaniline. Then a soluble polyimide(PI) containing fluorine and non-coplanar structure was obtained by one-step polycondensation reaction, and its structure and prop- erties were characterized. The results show that the PI has good solubility, high thermal stability, high op- tical transparency, and low dielectric constant. Key words: fluorinated polyimide; soluble; thermal stability; optical transparency; di