电石渣负载氟化钾的催化酯交换特性研究.pdfVIP

第42卷 第6期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No.6 2014年6月 Journal of Fuel Chemistry and Technology Jun. 2014 文章编号:0253鄄2409(2014)06鄄0690鄄07 电石渣负载氟化钾的催化酯交换特性研究 牛胜利,刘梦琪,路春美,李摇 辉,霍梦佳 (山东大学 能源与动力工程学院,山东 济南摇 250061) 摘摇 要:通过浸渍法制备以氟化钾为活性体、电石渣为载体的负载型钙基酯交换催化剂,并在借助X射线荧光光谱仪、热分析 天平、X射线衍射仪、氮气吸附鄄脱附仪、扫描电子显微镜以及哈米特指示剂法等手段对催化剂表征,以及气相色谱仪对原料油 成分分析的基础上,通过间歇式酯交换实验系统,从催化剂添加量、醇油物质的量比、酯交换温度与时间等影响因素出发,研 究了电石渣负载氟化钾催化花生油与甲醇酯交换的特性。 电石渣负载氟化钾后,产生KCaF 、CaF 以及KF等新物相,并且在 3 2 催化剂添加量为5%、反应温度为62益、反应时间为2h 以及醇油物质的量比为15 的酯交换条件下,能够取得91.58%的甘油 收率,相比较氢氧化钙和未有活性体负载的电石渣,其催化酯交换性能得到提高。 关键词:酯交换;催化剂;电石渣;氟化钾;负载 中图分类号:TK6摇 摇 文献标识码:A Catalytic performance of carbide slag loaded with potassium fluoride in transesterification NIU Sheng鄄li,LIU Meng鄄qi,LU Chun鄄mei,LI Hui,HUO Meng鄄jia (School of Energy and PowerEngineering,Shandong University,Jinan摇 250061,China) Abstract:Using the potassium fluoride as the active site and the carbide slag as the carrier,a calcium鄄based loaded catalyst for the transesterification was prepared through the impregnation method. The catalyst was characterized by X鄄ray fluorescence, thermogravimetric analysis , X鄄ray diffraction, nitrogen adsorption and desorption,scanning electron microscope and Hammett indicator. Also, the composition of peanut oil was analyzed by gas chromatograph. Then,the performance of prepared catalyst in the transesterification of peanut oil with methanol was examined with a batchwise experimental system. After being loaded with potassium fluoride,thenewtexturalphasesofKCaF ,CaF andKFemerge. Underthecondition ofthecatalystaddition of 3 2 5%,the transesterification temperature of 62 益,