AIE发光功能介孔二氧化硅纳米颗粒作为一种有效的荧光传感用于水下探测.pdf

Materials Letters 141 (2015) 176–179 Contents lists available at ScienceDirect Materials Letters journal homepage: /locate/matlet Amphiphilic ABC triblock terpolymer templated large-pore mesoporous silicas Dongpo Xu, Zhehao Huang, Lu Han, Yuan Yao n, Shunai Che n School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, P. R. China a r t i c l e i n f o a b s t r a c t Article history: The mesoporous silicas with two dimensional p6mm structure and interconnected three dimensional Received 9 July 2014 porous structure with large pore size of 16.9–18.0 nm were synthesized by the self-assembly of Accepted 15 November 2014 amphiphilic ABC triblock terpolymer, co-structure directing agent and silica source. Available online 26 November 2014 2014 Elsevier B.V. All rights reserved. Keywords: ABC triblock terpolymer Large pore Mesoporous silica Self-assembly 1. Introduction micro-phase separation to form micelles with hydrophobic core (PS and PEO) and hydrophilic shell (PAA). The negatively charged PAA and Ordered mesoporous materials with precisely controlled morphol- positively charged APS interact electrosta