Analysis of Solidification Path of FeCrNi Ternary Alloy.pdf

ISIJ International, Vol. 35 (1 995). No. 6, pp. 629-636 Analysis of Solidification Path of Fe-Cr-Ni Ternary Alloy Kenichi NAKAUE.1) KUDOH2) Susumu Masayuki and Toshio OHSASA. NARITA Division of Molecular Chemistry, Graduate School of Engineering. Hokkaido University, Kita-ku. Sapporo. Hokkaido. 060 Japan. Formerly Graduate Student, Hokkaido University. at Nisshin Steel Corporation, Shin-nanyo, Yamaguchi- 1 Now ) ken, 746 Japan. 2) Division of Materials Sciences and Engineering. Graduate School of Engineering. Hokkaido University. Kita-ku. Sapporo. Hokkaido. 060 Japan. (Received on January 5. 1995, accepted in final form on February 17. 1995) The solidification path of an Fe-Cr-Ni ternary alloy was calculated numerically on the basis of thermodynamicanalysis, In order to evaluate the effect of back diffusion in the solid, three modelsare used for the analysis. That is, I )a equilibrium model with perfect diffusion in the solid. 2) the Scheil model with no diffusion, 3) a limited back diffusion model, and obtained results were compared. In the calculations, the equilibrium tie line at the solid-liquid interface, which varies depending on both temperature and composition, was determined for each step of numerical computation. The solidification path with back diffusion wasc