Determination of the Effective Kinetic Diameter of the Complex Molecules.pdfVIP

_ _ - ~ 1 Cryst. Res. Technol. 1 21 1 1986 I 10 1 1299-1302 1 Dcpartmcut of Seiiiiconductors, Faculty of Phy#ics, Uuiversity of Sofia Determination of the Effective Kinetic Diameter of the Complex Molecules A iiiethotl for the eutiniation of the effective kinetic: diainetcr of the complex iiiolecules is suggested. The iiiethod is based on the ooiistructioii of a geometrical iiiodel by using the knowii data for the iiiteriiuolear distances a i d atoinic radii. On the basis of the sug- gestcd iiiethod tho values of the effective kinetic diaiiieter of some molecules for which there are no respective cxl~crinieiitaldata are calculated. rIpeAJIOlrceHMeTOA OUeHHH 3$$eKTMBHOrO KAHt?THIl?CKOIO AHaMeTpa CJIOmHbIX MOJIeKyn, OCHOBaHHbIi IIa nOCTpOeHAH IeOMeTpAqeCKOfi MOneJIA no H3BeCTHbIM AaHHblM 0 MelHny- RAePHbIX PaCCTOHHElfi A paAAyCOB BTOMOB. Ha OCHOBe IIpeAJIaraeMOrOMeTOAa BblIACJIeHbI 3HaIeHAR IIeKOTOPblX MOJIeKyJI, AJlR KOTOPbIX OTCYTCTBYIO COOTBeTCTBYIOUHB 3KCnepH- MeHTaJlbIIbIC fiaIIIIbIe. 1. Introduction The main troubles for the calculatio~iof the diffusion coefficient of the gaseous sub- stances are brought about by that in the literature are published quite a few data on the effective kinetic diameter of the molecules. The lack of these data can be explained with the experimental complexity of the determination of this quantity (KAFAROV; MELVIN-HUSE). By reason of this the possibility for estimation of the effective kinetic diameter value of the diffusing particles on the basis of the indirect data acquires a particularly worth. According to the models accepted