CoCu多层纳米线阵列的制备与磁性能.pdf

理化学学报(Wuli Huaxue Xuebao) 1306 A cta Phys. Chim. Sin., 2007, 23(8) ：1306-1310 August [Note] Co/Cu 多层纳米线阵列的制备与磁性能 素薇 宋振兴 王宏智 (天津大学化工学院应用化学系杉山表面技术研究室, 天津 300072) 摘要： 利用双槽直流电沉积技术在阳极氧化铝(AAO)模板的纳米孔中获得调制波长为50 和200 nm 的Co/Cu 多层纳米线, 多层纳米线的调制波长由电沉积时间控制. 运用扫描电子显微镜(SEM)和透射电子显微镜(TEM)表征 纳米线的形貌, Co/Cu 多层纳米线的长度约20 滋m, 直径约80 nm; 用X 射线衍射(XRD)研究多层线的结构; 用振 动样 磁强计(VSM)测试纳米线阵列的磁性能; 利用可变磁场结合高灵敏度恒流装置研究巨磁电阻(GMR)特性. 结果表明, Co/Cu 多层纳米线具有磁各向异性. 当磁场与纳米线平行和垂直时, 调制波长为50 nm 的多层线的矫 顽力分别为87500 和34200 A ·m-1, 而调制波长为200 nm 的多层线阵列的矫顽力分别为28600 和8000 A ·m-1. 调制波长为50 nm 的多层纳米线的磁电阻变化率高达-75豫, 而调制波长为200 nm 的多层线未产生明显的 GMR 效应. 关键词： Co/Cu; 多层纳米线; GMR; 自旋扩散长度; XRD 中图分类号： O646 Fabrication and Magnetic Properties of Co/Cu Multilayer Nanowire Arrays YAO Su Wei SONG Zhen Xing WANG Hong Zhi (S UGIYAMA Laboratory of Surf ace Technology, School of Chemical Engineering and Technology, Tianji n University, Tianjin 300072, P. R. China) Abstract ：Co/Cu multilayer nanowire arrays embedded in anodic alumina (AAO) template were successfully prepared by dual bath electrodeposition technique. SEM and TEM indicated that the Co/Cu nanowires were regularly spaced and uniform in shape with lengths of about 20 滋m and diameters of 80 nm. The bilayer thicknesses of the two samples were 50 nm and 200 nm respectively. XRD test indicated that the Co and Cu grew in their (hcp) and (fcc) polycrystal structures, respectively. VSM test indicated that nanowire arrays had apparent magnetic anisotrop