《Effects of Protein on the Detection of Chlorobenzenes in Fish and Their Elimination by Modified QuEChERS Method》.pdfVIP
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Chem.Res.Chin.Univ.2013,29(6),1063--1067
in
ontheDetectionofChlorobenzenes
EffectsofProtein
Modified
FishandTheirElimination
by
Method
QuEChERS
DENG ZHANG andLIU
Qiao·qiao,LIGui-zhi,LIUPei-pei, Xing.mei Yong.ming+
Yantai R.China
andChemical 264005,P
University,Yantai
CollegeofChemistry Engineering,
AbstractMolecularfluorescence and spec·-
spectrometry,resonanceRayleighscatteringgaschromatography‘。mass
wereusedto theeffectof fishserum themodel ontheextrac-
troscopy(GC.MSlstudy pure albumin(FSA)asprotein
tionofthree and
chlorobenzenes(CBs:1,3-DCB,l,2-DCB
thattherewasa effectbetweenCBandFSA.Inan
fish resultsshow
zene)insamples.The strongbinding aqueous
solutionof slowbutfull denaturationtake wouldcause
fractionlacetone,a
90%(volume protein mightplace,which
the of andthe ofCBs.Basedonthese
unfoldingprotein releasing results,a
with solutioninthe
and wasmodified thetraditionaIacetonitrile
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