《Hydrothermal syntheses and characterization of three lanthanide coordination complexes constructed by 22 62terpyridine and 22biphenyldicarboxylic acid》.pdfVIP
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Availableonlineat1^n^,v讥sciencedirect.corn
.一,, 冀阿瞳.I^LoF
峰弓,ScienceDirect 腿E』l硼限S
JOURNALOFRARE
塑一 EARTHS,VoL30,No.3.Mar.2012,P.256
andcharacterizationofthreelanthanide
Hydrothermalsyntheses
constructed and acid
2,2’:6’,2”-terpyridine
complexes by
XIE Danyu(龚丹宇),WEIDanyi(魏丹毅)
Hongzhen(谢洪珍),ZHANGYanguang(张燕广),GONG
Base FunctionalMaterialsand ScienceandChemfcal
(StateKeyLaboratory PreparationScience,FacultyofMaterials Engineering,MngboUniversity,Ningbo
ofNovel
315211,China)
Received17 201 29 2011
August1;revisedAugust
and
Abstract:Two1Dcoordination 1,Yb acid tpy=
polymers[Ln2(dpdc)3(tpy)2’H20L[Ln=Nd2,H2dpdc=2,2’-biphenyldicarboxylic
onedinuclear 3wereobtainedvia reactionsanddetermined
2,2’:6’,2-terpyridine]andcomplexEr2(dpdc)2(Hdpdc)2(tPY)2hydrothermal by
diffaction structuredataof1and2revealedthattwoCOOrdinationwereisostructuraland a1D
X.ray analysis.Thecrystal polymers possessed
in
chainframework of the unit.thetwo 3werebothnine.coordinated
consistingeight-coordinatedLn(III)centers.Inasymmetric Er(III)ions
andhadsimilarcoordinationenvironments.Thewere intodinuclearstructures.1f11ewere
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