Li1.2(Ni0.4Mn0.4)x(Co0.4Mn0.4)1-xO2(0≤x≤1)系列富锂材料的制备及性能.pdf

里整筮至团囝蛋目圜衄 制备及性能 彭庆文，卢志威，任丽彬，刘兴江，刘浩杰 (中国电子科技集团公司第十八研究所化学与物理电源重点实验室，天津300384) 摘要：富锂材料具有大于200mAhlg的可逆比容量。吸引了广大研究者的目光，成为近年来的研究热点。从材料相图出 衍射(XRD)、扫描电子显微镜(SEM)进行了结构和形貌分析、并对材料的电化学性能进行了测试分析。结果表明所得 种材料的首次放电比容量逐渐增大，循环性能逐渐提高。 关键词：Li，。(Ni。4Mn04)』C004Mn。4)，一J。2；富锂材料；锂离子电池 中图分类号：TM912 文献标识码：A 文章编号：1002—087 X(2013)03—0354—04 andcharacteristicsoflithium-rich Synthesis Lil．2(Nio．Aino．4)f (Coo．4Mno．4)1一x02(O≤X≤1) PENG Qing—wen，LUZhi—wei，RENLi-bin，LIUXing-jiang，LIUHao-jie and onPowerSourccs InstituteofPower 300384，China) (ScienceTechnology Laboratory,TianjinSources,Tianjin Abstract：Lithium—-richmaterialwhichdeliveredareversible than200 hasattractedintense capacityhigher mAh／g done to attentionofresearchersallovertheworld this was recently．Inwork，materialdesign accordingphase acetatesolidreactionmethod． djagram．Lithium-richLil2(Ni04Mnn4)x(Coo．4Mnn4)1一p2(0≤x≤1)werepreparedby Inductive emission atomic coupledplasmaoptical spectrometry(ICP—OES)andabsorption to their electron appliedanalyzecompositions；X—raydiffraction(XRD)andscanning tocharacterizethestructureand of electro- employed morphology chemical ofthe werealso resultsshowthatallthefivelithium—richmaterialsare propertiessamples analyzed．The testsshowthatthefirst andthe