有机基Fe_3O_4磁性液体的制备和表征.pdfVIP

有机基Fe304磁性液体的制备和表征 黄小忠，周娟娟，周克省，杜作娟 (中南大学物理科学与技术学院，湖南长沙410083) 摘要：用油酸作为表面活性荆，采用化学共沉淀法制备纳米级Fe304磁性粒子，以此制备有机磁性液体。 实验研究了Fe2+／Fe3+配比、不同的制备路线、表面活性剂的用量三个方面对磁流体的影响，并分析了这些因素 备路线二，制备0．OlmolFe，04表面活性剂用量为0．7ml。产物在油酸包裹后基本全部萃取到有机相，且分散均 匀。XRD分析证实了产物为纯Fe，04磁性粒子，平均粒径为50rim左右。 关键词：有机基磁流体；Fe304；化学共沉淀法；工艺条件 中图分类号：TM271：TB383文献标识码：B 文章编号：1001—3830(2010)01．0036．04 FabricationandCharacterizationof Fluid organic-basedFe304Magnetic HUANG Juan-juan，ZHOUKe-sheng，DUZuo-juan Xiao—zhong，ZHOU School Scienceand South Technology,Central 410083，China ofPhysical University,Changsha this nano—·sized were chemical Abstract：In Fe304 oleic paper,the particlespreparedby CO-precipitationusing acidassurfactant．Theinfluenceof ofsurfactantonthe Fe”／Fe”ratio，preparationroutes，anddosage magnetite wasstudied．Thenstudiesaremadeindetailonthe mechanismof fluid．Asa particles influencing Fe304magnetic result， thereasonableconditionsof with diameterand process preparingFe304 highpurity,smallparticle homogeneous route ofsurfactantWas were 0．7m1．The dispersiondetermined：n(Fe2+)：n(Fe”)=l：1．65，preparation2，dosage coatedoleicacidare extractedto inbasefluid．The particlesby completely organicphase，andhomogeneouslydisperse XRD confirmsthatthe are an diameterofabout50nm． magnetite averag