《LiClKClMgCl2Gd2O3熔盐共电沉积制备MgLiGd合金(英文期刊)》.pdfVIP

Electrochemical codeposition of Mg-Li-Gd alloys from LiCl-KCl-MgCl -Gd O melts 2 2 3 1, 2 1 1 1 1 1, 3 WEI Shu-quan , ZHANG Mi-lin , HAN Wei , YAN Yong-de , ZHANG Meng , ZHANG Bin 1. Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, Harbin Engineering University, Harbin 150001, China; 2. College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China; 3. Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, China Received 25 September 2010; accepted 21 December 2010 Abstract: Mg-Li-Gd alloys were prepared by electrochemical codeposition from LiCl-KCl-MgCl -Gd O melts on molybdenum 2 2 3 electrode with constant current density at 823 and 973 K. The microstructure of the Mg-Li-Gd alloys was analyzed by X-ray diffraction (XRD), optical microscopy (OM) and scanning electron microscopy (SEM). The results show that magnesium and gadolinium deposit mainly in the first 30 min, and the alloy obtained contains 96.53% Mg, 0.27% Li and 3.20% Gd (mass fraction). Then, the reduction of lithium ions occurs quickly. The composition of alloy can be adjusted by controlling electrolysis time or Gd O concentration in LiCl-KCl melts. With the addition of Gd into Mg-Li