《Microstructure and microwave dielectric properties of CaOB2O3SiO2 glass ceramics with various B2O3 contents》.pdfVIP
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10.1007/s11771-011-0846-8
Microstructureandmicrowavedielectricpropertiesof
CaO-B2O3-SiO2glassceramicswithvariousB2O3contents
WEIPeng-fei1,2 ZHOUHong-qing1 ZHUHai-kui1
DAIBin1 WANGJie1
1.CollegeofMaterialsScienceandEngineering,NanjingUniversityofTechnology,Nanjing210009,China;
2.CollegeofMaterialsEngineering,JinlingInstituteofTechnology,Nanjing211169,China
Abstract:TheeffectsofB2O3additiononboththesinteringbehaviorandmicrowavedielectricpropertiesofCaO-B2O3-SiO2(CBS)
glassceramicswereinvestigatedbyFouriertransforminfraredspectroscopy(FTIR),X-raydiffractometry(XRD)andscanning
electronmicroscopy(SEM).TheresultsshowthattheincreasingamountofB2O3causestheincreaseofthecontentsof[BO3],[BO4]
and[SiO4],whichdeducestheincreaseofCaB2O4anda-SiO2andthedecreaseofCaSiO3correspondingly.Nonewphaseis
observedthroughouttheentireexperiments.Abulkdensityof2.54g/cm3,athermalexpansioncoefficientvalueof11.95× 10-6℃-1
(20-500℃),adielectricconstant εrvalueof6.42andadielectriclosstanδ valueof0.0009(measuredat9.7GHz)areobtainedfor
CBSglassceramicscontaining35%B2O3(massfraction)sinteredat850℃ for15min.
CaO-B2O3-SiO2;B2O3content;Fouriertransforminfraredspectroscopy;microstructure;dielectricproperties
Project(2007AA03Z0455)supportedbytheNationalHigh-TechnologyResearchandDevelopmentProgramofChina;Project(BE2009168)
supportedbytheNaturalScienceFoundationofJiangsuPrownceinChina;ProjectsupportedbythePriorityAcademicProgram
DevelopmentofJiangsuHigherEducationInstitution,China
2010-07-15 2010-10-08
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