《MgZnAl三元系富镁角335°C等温截面（英文版）》.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 3405−3412 Isothermal section of Mg-rich corner in Mg−Zn−Al ternary system at 335 °C Yu-ping REN, Shi-neng SUN, Li-qing WANG, Yun GUO, Hong-xiao LI, Song LI, Gao-wu QIN Key Laboratory for Anisotropy and Texture of Materials, Ministry of Education, Northeastern University, Shenyang 110819, China Received 24 November 20 13; accepted 14 July 2014 Abstract: The phase equilibria and compositions at the Mg-rich corner of the Mg−Zn−Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). It is experimentally testified that the α-Mg solid solution is not in equilibrium with the Mg32(Al, Zn)49 (τ) ternary intermetallic compound or q quasicrystalline phase, but only in equilibrium with one ternary intermetallic compound Al5Mg11Zn4 (φ). The whole composition range of the φ phase was also obtained at 335 °C, i.e., 52.5%−56.4% Mg, 13.6%−24.0% Al, 19.6%−33.9% Zn (mole fraction). The solubility of Al in the MgZn phase is remarkably more than that in the Mg Zn phase, and the maximum is about 8.6% Al. Aluminum and zinc are simultaneously soluble in the α-Mg solid 7 3 solution. Key words: Mg−Zn−Al ternary system; isothermal section; τ intermetallic compound; solubility h. It is thought that the annealing time is too short to 1 Introduction achieve the phase equilibrium relations