均四甲苯的制备方法及应用研究.pdfVIP

·64 · 殷丽娜等：均四甲苯的制备方法及应用研究 Vol． 31． No． 6 ，2009 均四甲苯的制备方法及应用研究 2 1 1 殷丽娜 ， 胡永玲 ， 韩大维 （1.黑龙江省科学院石油化学研究院,黑龙江 哈尔滨 150040；2.黑龙江大学 化学化工与材料学院,黑龙江 哈尔滨 150080） 摘要: 均四甲苯是一种重要的有机化工原料,主要用于生产均苯四甲酸二酐,因而也是生产聚酰亚胺绝缘薄膜的最经济、 最理想的原材料。聚酰亚胺在耐热性工程塑料中占有极为重要的位置,是目前热塑性工程塑料中耐热性最好的品种之一，广泛 应用于航空、航天、机电及电子等领域。详细介绍了均四甲苯的性能和用途、生产方法、反应机理及分离提纯的方法。通过比较可 知,四甲苯异构化制备均四甲苯的工艺,具有原料利用率高、经济效益好等优点，经济可行。 关键字:均四甲苯；均苯四甲酸二酐；聚酰亚胺 中图分类号：TQ 241.12 文献标识码：A 文章编号：1001- 0017(2009)06- 0064- 05 Preparation and Application of Durene 2 1 1 YIN Li-na , HU Yong-ling and HAN Da-wei (1. Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, China; 2. College of Chemistry Material Engineering, Heilongjiang University ,Harbin 150080, China) Abstract: Durene is an important organic chemical raw material, and it is mainly used to produce pyromellitic acid dianhydride, therefore, the durene is considered as the most economical and ideal raw material to produce polyimide film. Polyimide, as heterocyclic aromatic polymers, keeps an important position in the heat-resistance engineering plastics, and is one of the products with the best heat resistance at present. Polyimide is widely used in aerospace, aviation, electromechanical electronic fields. The properties and applications of durene, preparation methods ，reaction mechanisms, and purification methods are reviewed. In comparison with others, C 10 aromatic hydrocarbon resources are centralized. The preparation of durene by i － somerization of tetramethylbenzene is an economically feasible course, wh