臭氧沸石工艺处理水中硝基苯的效能研究.pdfVIP

第 28 卷第 4 期 环 　　境 　　科 　　学 Vol . 28 ,No . 4 2007 年 4 月 ENVIRONMENTAL SCIENCE Apr . ,2007 臭氧沸石工艺处理水中硝基苯的效能研究 秦庆东 , 马军 ,刘可 ,杨忆新 ( 哈尔滨工业大学市政环境工程学院 ,哈尔滨 　150090) 摘要 :在连续反应器中 ,考察了臭氧沸石工艺在不同条件下去除硝基苯的效果. 结果表明 ,臭氧沸石工艺对硝基苯的去除效 率明显高于单纯臭氧氧化 ,反应 7 min 后 ,硝基苯去除率达到 100 % ,并且该反应符合假一级反应动力学. 叔丁醇能抑制臭氧沸 石工艺对硝基苯的去除效率 ,表明在氧化去除硝基苯过程中羟基自由基起主导作用. 增加沸石投量和臭氧浓度均能有效地提 高臭氧沸石工艺对硝基苯的去除效率 ,并且臭氧沸石工艺对硝基苯的去除速率与沸石投量之间存在 1 个最优值 ,与臭氧浓 度呈线性关系. 臭氧沸石工艺对硝基苯的去除速率与初始硝基苯浓度无关. 离子强度对臭氧沸石工艺降解硝基苯的效率影 响较大 ,当离子强度从 0 增加到 1 ×10 - 3 molL 时 ,臭氧沸石工艺对硝基苯的去除率从 812 %降低至 316 %. p H 值主要影响臭 氧的分解能力 ,随着溶液 p H 降低 ,臭氧沸石工艺对硝基苯的去除效率逐渐下降. 沸石具有较长的使用寿命. 关键词 :臭氧 ;沸石 ;硝基苯 ; 自由基 ;离子强度 ( ) 中图分类号 :X52 ; TU9912 　文献标识码 :A 　文章编号 2007 Eff iciency Study on Nitrobenzene Removal by OzoneZeolite Process QIN Qingdong , MA Jun , L IU Ke , YAN G Yixin ( School of Municipal and Environmental Engineering , Harbin Institute of Technology , Harbin 150090 , China) Abstract: Degradation of nitrobenzene by ozonezeolite process was investigated in a continuous flow reactor The results showed that nitrobenzene was degraded by ozonezeolite process efficiently in comparison to ozone alone . The removal of nitrobenzene was 100 % in 7 minutes. The reaction followed p seudofirstorder kinetics. By investigating the effect of scavenger on nitrobenzene removal , it is concluded that nitrobenzene was mainly degraded by hydroxyl radicals in solution . Increasing zeolite dosage and ozone concentration also enhanced nitrobenzene removal . However , there was an optimum removal rate among zeolite dosages. The relationship between the ozone concentrations and the kinetic constants was linear . At the same time , nitrobenzene decomposition was inde