Performance and Mechanisms of Fluoride Removal from Groundwater by Lanthanum-aluminum-loaded Hydrothermal Palygorskite Composite.pdfVIP
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Performance and Mechanisms of Fluoride Removal from Groundwater by Lanthanum-aluminum-loaded Hydrothermal Palygorskite Composite.pdf
Chem.Res.Chin.Univ.,2015,31(1),l44一l48 doi:l0.1007/s40242.O15-4126.2
PerformanceandM eehanismsofFluorideRemovalfrom
GroundwaterbyLanthanum-a·luminum--loaded
HydrothermalPalygorskiteComposite
ZHANGShengyu,,LOYing ,LINXueyu ,ZHANGYuling’andSUXiaosi,
. KeyLaboratoryofSongliaoAquaticEnvironment,MinistryofEducation,
JilinJianzhuUniversity,Changchun130118,P R.China,
2.KeyLabofGroundwaterResourcesandEnvironment,MinistryofEducation,
3.InstituteofWaterResourcesandEnvironment,JilinUniversiyt,Changchun130021,PR.China
Abstract Lanthanum-aluminum loadedhydrothermalpalygorskite(La—Al-HP)compositewaspreparednadselected
asadsorbentforthefluorideremovalfrom simulated groundwater.Theadsorbentwaschraacterized by scanning
electronmicroscopy(SEM),Brunauer-Emmet-Teller(BET)naalysis,X—raydiffraction(XRD)naalysisandX-raypho—
toelectronspectroscopy(XPS).SEM visualizationshowsthatthedensesurfacestructureofrawHPappearedloose
andpresentedmicrocanalsaftermodification.TheBET na alysisalsoprovedthespecificsurfaceareaOfLa-Al-HP
composite(95.58m2/g)washigherthanthatofmerawHP(34.31m2/g).Subsequently,theadsorptioncapacityof
La.A1.HP compositewasdemonstrated in adsorption experiments.Thekineticsoffluoride ion adsorption into
La.Al。HPcompositefollowedthepseudo-secondorderwithacorrelationcoe衢 cientof0.997.Theisotherm datawas
wellfittedwiththeLnagmuirmode1.ThemonolayeradsorptioncapacityofLa-Al-HPcompositewas1_30medg.The
XRD andXPSresultsrevealthathteL andAlj ionswereloadedonthesurfaceofmodifiedHPandthefluoride
ionwasadsorbedontotheLa-Al-HPcomposite.A lrageamountofLa.Al-0 compositeoxideexistingonthesurface
ofLa.A1.HPcompositemightbetheimmanentcausefortheexcellentadsoprtioncapacityof
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