《2016春-北京化学会化学竞赛培训-晚间讲座-ppt》.pdfVIP

AN INTRODUCTION OF ORGANOMETALLICS CHEMISTRY 周志尧 zzytaxol@ 2012/2/3 CONTENT Basic Theory General Properties Examples Problems BASIC THEORY Ligand Field Spectrochemical Series: I− Br− S2− SCN− Cl− NO − N − F− OH− C O 2− 3 3 2 4 H O NCS− CH CN py NH en bipy phen NO − 2 3 3 2 PPh CN− CO 3 BASIC THEORY Ligand Field BASIC THEORY Ligand Field Weak Field Ligand: Strong Field Ligand: - F , H O, etc. CO, PF , etc. 2 3 BASIC THEORY Hard-Soft Acid-Base Hard acids tend to bind to hard bases. Soft acids tend to bind to soft bases. Pearson, R.G. J. Am. Chem. Soc. 1963, 85, 3533-3539 BASIC THEORY Trans Effect - - - - - H PR , CO, CN I Br Cl NH H O 3 3 2 Good σ donor: