《纳米氧化铝前驱体AlOOH的微观晶体结构分析2016年论文》.pdfVIP

3 期 纳米 科 技 灾燥造援12 燥援3 圆园15 年6 月 葬灶燥泽糟蚤藻灶糟藻 驭 Nanot藻糟澡灶燥造燥早赠 June 圆园15 Micro Crystal Structure Analysis about Precursor AlOOH of Nano-alumina 1 1 2 2 HAO Bao-hong ，HE Qi ，ZHANG Hai-long ，WANG Peng-yue （1. Department of Mechanical Engineering，Beijing Institute of Petrochemical Technology， Beijng 102617 ，China） （2. Ministry of transport and Road Research Institute ，Beijng 100088，China） Abstract: The nano Al2O3 has good application foreground in many fields as the properties of adsorption and catalytic activity. In order to reveal the mechanism and the characteristic of crystal structure of heterotypic nano alumina in a composite system. Utilized leading metal embedded slicing micron -nano representation method at home and abroad, to analyze the microcrystal structure of heterotypic nano AlOOH products particularly, revealed the acting mechanism of isomorphous replacement of iron ions and intercalation of sulfate ions from the polar additive in the crystal growing process, and pointed out the surface restoration function of the nano AlOOH crystalline surfaces from the polar surfactant additive. The correcfness of the conclusion was verified by using energy spectrum and infrared spectrum. Keywords: nano-Al O ; polar additive; AlOOH; microcrystal structure; isomorphous replacement 2 3 米氧化铝前驱体AlOOH的微观晶体结构分析 1 1 2 2 郝保红，何 琦