《A New Three-dimensional Supramolecular Polymer Built from Non-covalent Bonding Interactions》.pdfVIP

33卷 4期 结 构 化 学 (JIEGOUHUAXUE) VO1．33．No．4 2014．4 Chinese Struct． Chem． 557—562 A New Three-d·imensionalSupramolecularPolymar Builtfrom Non．covalentBondingInteractions① CHENShui．Sheng~ QIAORui SHENGLiang—Quan YANGSong (CollegeofChemistry＆ChemicalEngineering,FuyangNormalCollege，Fuyang236041，China) ABSTRACT Anew complex，[Ni2(L)4(H20)8](1，L1=4-(1H-imidazol一4一y1)benzoicacid)，has beenhydrothermallypreparedandcharacterizedbysingle—crystalX-raydiffraction，IR spectroscopy， elementalanalysisandPXRD．Complex 1crystallizesinmonoclinic，spacegroupP2~／cwitha 22．281(2)，b=7．3959(7)，c=24．978(3)A，=90．876(10)，v=4115．6(7)A ，z 8，C2oH22N4OgNi， Mr=505．13，D =1．630g／cm， =1．001mm～，S：1．080，F(000)=2096，thefinalR=0．452and wR=0．1152for9380observedreflections(，|2 J)『)．TheresultofX—ray diffractionanalysis revealedthreedifferentkindsofNi(II)centremononucleramoleculesintheasymmetricunit．The independentmononuclearunitsraebridgedtoofrm athree—dimensionalsupramoleculra polymerby extensivehydrogenbondsnadC-H…7t-non—covalentbondinginteractions． Keywords：synthesis，supramolecularpolymer,non-covalentbondinginteractions 1 INTRoDUCTIoN acid and 3,5-di(imidazol-1·y1)benzoic acid，are employedas goodcnadidatesofrtheconstructionof novelMOFsinourpreviousstudy[10-12]Takingthe The design and synthesisoffunctionalmetal— ． orgnaicframeworks(MOFs)bytheself-assemblyof favorablecoordinationabilityofN／O--donordifunc·· organiclignadswithappropriatefunctionalgroups tional groupsintoaccount，wedesignanovel1H- and metalionsa