《Highly ordered arrangement of meso-tetrakis（4-aminophenyl）porphyrin in self-assembled nanoaggregates via hydrogen bonding》.pdf

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《Highly ordered arrangement of meso-tetrakis（4-aminophenyl）porphyrin in self-assembled nanoaggregates via hydrogen bonding》.pdf

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ChineseChemicalLetters25(2014)752—756 ContentslistsavailableatScienceDirect ChineseChemicalLetters journalhomepage：www．eIsevier．com／Iocate／ccIet Originalarticle Highlyorderedarrangementofmeso--tetrakis(4-- ⑩cmss aminopheny1)porphyrininself-assembled nan0aggregatesviahydrogenbonding Qing—YunLiu，b，．Qing—YanJiab．Ji—OinZhub QianShaob，Jun—FengFanb． _ ， Dong—M eiW angb ． Yan—ShengYin · CollegeofChemistryandChemicalEn neering,OceanUniversityofChina．OJngdao266100，China CollegeofChemicalandEnvironmentalEngineering,ShandongUniversiytofScienceandTechnology，Odngdao266510，China InstituteofMarineMaterialsScienceandEn neering,ShanghaiMaritimeUniversiyt，Shanghai201306．China A RT IC L E IN F0 A BS TR A CT Articlehistory： meso—Tetrakis(4一aminopheny1)porphyrin(1．APP1canself-assembleintonanostructureswithdifferent Received6November2013 morphologiesbyaphase—transfermethod．Themorphologies(nanospheres，nanorodsandnanothorns) Receivedinrevisedform 27December2013 ofporphyrinnanoaggregatescouldbeeasilytunedjustbychangingtheconcentrationofporphyrinina Accepted30December2013 propersolvent atroom temperature．HRTEM images revealed the formation ofhighly ordered Availableonline25January2014 supramoleculararraysofTAPP，f．e．，superlatticeofTAPPmoleculesinnanoaggregates．whichagreedwell withthesizeofonemoleculeofTAPP．UV—visabsorptionspectrashowedanobviousredshiftoftheSoret Keywords