《锂离子电池用LiVPO4FC 基正极材料的制备和性能(英文期刊)》.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 1718−1722 Synthesis and performance of LiVPO4F/C-based cathode material for lithium ion battery Jie-xi WANG, Zhi-xing WANG, Li SHEN, Xin-hai LI, Hua-jun GUO, Wei-jia TANG, Zhen-guo ZHU School of Metallurgy and Environment, Central South University, Changsha 410083, China Received 25 July 2012; accepted 17 January 2013 Abstract: LiVPO F/C-based material was prepared by heating a precursor, which was obtained through ball milling with slurry of 4 H C O ·2H O, NH H PO , NH VO and LiF. In this process, H C O ·2H O was used as a reducing agent as well as carbon source. 2 2 4 2 4 2 4 4 3 2 2 4 2 The properties of the precursor and the prepared sample were characterized by TG-DTA, XRD, SEM, TEM and C−S analysis. XRD analysis shows that the precursor is amorphous and the prepared LiVPO F sample coexists with Li V (PO ) , as well as a small 4 3 2 4 3 amount of V O . Homogeneous powders with an average particle size of 2 μm are observed by TEM. HRTEM image shows that the 2 3 crystal particles are coated by amorphous carbon uniformly, with a coating layer of about 2 nm. The synthesized material shows the specific discharge capacities of 151.3 and 102.5 mA·h/g at 0.1C and 10C respectively, in the voltage range of 3.0−4.4 V, and it keeps 90.4% of initial discharge capacity at 10C after 50 cycles. V3+/V4+ redox peaks corresponding to both LiVPO F and Li V (PO ) are