用于柴油脱硫离子液体的再生研究本科毕设论文.docVIP

摘 要 离子液体具有熔点低，蒸气压低，电化学窗口大，酸性可调节及良好的溶解度、黏度和密度等特点，在有机反应中不但可以代替普通有机溶剂，，[Bmim]FeCl4)，研究了离子液体的黏度和电导率随温度的变化，并对它们进行拟合。采用循环伏安法研究了Fe(III)/Fe(II)在[Bmim]FeCl4Fe3+扩散控制的可逆过程，但是发现Fe3+没有完全还原为Fe2+，40℃时转移的电子数仅为0.3，Fe(III)在[Bmim]FeCl4Arrhenius公式，kJ/mol，进一步的电解表明合适的电解电压为-1.6V，电流密度随温度的升高而增加，乙二醇不能有效提高铁基离子液体的电导率。 关键词：[Bmim]FeCl4，离子液体，电解，循环伏安法，电化学行为 Abstract Ionic liquids have properties of low melting point,low vapor pressure,wide electrochemical window,adjustable acidity,strong solubility,high viscosity and so on.Ionic liquids (ILs) have been applied in many fields of industry process and science research in world in recent years.With increasing application,synthesis of ILs andphysicochemical and thermo physical properties of ILs are required. This article used [Bmim]FeCl4 made by us,the changing of Ionic liquids viscosity and conductivity with temperature were studied and fitted.The electrochemical behaviors of Fe(Ⅲ)/Fe(Ⅱ) redox couple in [Bmim]FeCl4 system were investigated by cycle voltammetry.the results showed that the process was a diffusion-controlled reversible process.But that did not fully change Fe3+ to Fe2+,at 40℃ the number of electrons transferred only 0.3.The relationship between diffusion co-efficient and temperature agreed well with the Arrhenius equation.Reduction peak current increases with increasing temperature ,the diffusion activation energy of Fe(III) in [Bmim]FeCl4 system was 23.288kJ/mol.Further electrolysis showed that the proper electrolytic voltage was -1.6V and current density increased with increasing temperature,Ethylene glycol can not improve the conductivity of iron-based ionic liquids. Key words：[Bmim]FeCl4Ionic liquid, Electrolysis,Cyclic voltammetry electrochemical behavior 毕业设计（论文）原创性声明和使用授权说明 原创性声明 本人郑重承诺：所呈交的毕业设计（论文），是我个人在指导教师的指导下进行的研究工作及取得的成果。尽我所知，除文中特别加以标注和致谢的地方外，不包含其他人或组织已经发表或公布过的研究成果，也不包含我为获得 及其它教育机构的学位或学历而使用过的材料。对本研究提供过帮助和做出过贡献的个人或集体，均已在文中作了明确的说明并表示了谢意。 作 者 签 名：　　 　 　　日　 期：　　 　 　　 指导教师签名：　　 　 　　 日　　期：　　 　 　　 使用授权说明 本人完全了解