高分子反应原理.pptVIP

2. The factors of influencing active site forms Solvent The polymerization is much faster in the more polar solvent, because it has much solvating power. The dielectric constant 介电常数 is not a quantitative measurement. Table Effect of solvent on anionic polymerization of styrene Solvent Dielectric constant (ε ) Kpapp (liter/mole-sec) Benzene 2.2 2 Dioxane 2.2 5 THF 7.6 550 1,2-Dimethoxy ethane 5.5 3,800 Counter ion 反离子 Li+ 160 2.2 0.94 Na+ 80 1.5 3.4 K+ 60-80 0.8 6.5x104 19.8 Rb+ 50-80 0.1 21.5 Cs+ 22 0.02 24.5 Counterion Polymerization in THF kp ± for dioxane Kp± Kx107