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高分子物理课件(复旦大学)chapter4-5.ppt
Poisson’s raindrop problem If raindrops fall randomly on a pond creating expanding circular waves, what is the chance that the number of waves created by different raindrops which pass over a representative point P up to time t is exactly n? Kinetics models of overall crystallization-Avrami 2.Impingement model P Poisson distribution What is the chance that no wave reaches a given point P in space ? heterogeneous homogeneous The Avrami equation for 3D E(t): wave spreading area during t While t or v is very small or Thermodynamics of Crystallization: 1. Melting point of Lamellar Crystals Therm
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