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ABSTRACT
be
Inthefieldofmodemehiral dividedinto
synthetic may
chemistry,catalyticasymmetricsynthesis
three additiontotransitionmetal ttlird
and transformations，the
types．In enzymatic general
catalysis
tothe of hasnOW
approachcatalyticproductionenantiomericallypureorganiccompoundsemerged：
are low-molecular-weitht
Asymmetric molecules，i．e．
Organocatalysis．Organocatalystspurely organic
and transitionmetalsand
composed
of(mainly)carbon，hydrogen，nitrogen，oxygen，sulfurphosphorus，not
other ale tohandleand stabletoward andwaterandCanbe
metals．Organocatalystseasy generally oxygen
fora be
stored oftime．Froma of should
longperid practicalpointview,organocatalysts
and to ofthese have
friendlyapplicablelarge-scalesynthesis．Becauseadvantages，organocatalystsplayed
an
ever and rolein
increasingimportantcatalyticasymmetricsynthesis．
acrucialfunctionalrolein toan
Hydrogenbondingplays organocatalysis，becausehydrogenbonding
selvestodecreasetheelectron ofthis ittoward attack．
electrophile density nucleophilic
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