Synthesis of MoSe2 nano-flakes modified with dithiophosphinic acid extractant at low temperature.docVIP

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Synthesis of MoSe2 nano-flakes modified with dithiophosphinic acid extractant at low temperature.doc

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Synthesis of MoSe2 nano-flakes modified with dithiophosphinic acid extractant at low temperature.doc

Synthesis of MoSe2爊anoflakes modified with dithiophosphinic acid extractant at low temperature Abstract Flake-like MoSe2爊anomaterials were successfully synthesized via a chemical reaction in the mixed medium of ethanol and water (Vethanol:Vwater??:7) at 70牥C using di-(2, 4, 4-trimethylpentyl) dithiophosphinic acid extractant as surface-modifying agent, home-made NaHSe as Se source, Na2MoO4?H2O as Mo source and NH2OH稨Cl as reducing agent. The MoSe2爏amples were characterized with XRD, TEM and EDXS, respectively. The results indicated that the morphologies of MoSe2燾ould be controlled by the concentration of extractant in the system, and flake-like MoSe2爓ith a diameter of about 70爊m was obtained when the addition amount of extractant was 0.75爂稬??1. Keywords Flake-like;? MoSe2;? Dithiophosphinic acid;? Chemical reaction 1. Introduction Transition molybdenum dichalcogenides MoX2?(X?=?S, Se) have drawn considerable attention due to their technological importance?[1],?[2]燼nd?s[3]. The same as MoS2, MoSe2燼lso has an interesting sandwich structure: layers of Se朚o朣e are loosely bounded to each other by weak Van der Waals forces? 70[4]. Due to the novel structure, MoSe2爃as numerous applications, such as an intercalation host?o[5], electrode in high-energy density batteries?[6], lubricant?[7], catalysts?[8]燼nd spaceflight?i[9]. Traditionally, crystalline MoSe2was synthesized by solid-state reaction between molybdenum and selenium elements at least 900牥C for several days?s[10]. Crystalline MoSe2爌roduct was also obtained rapidly via the metathetical reaction between high-valent molybdeunm halide and alkali-metal selenide, which was known as self-propagating high-temperature synthesis (SHS)?c[11]. Due to self-released heat, this reaction system might reach a high temperature of 1050牥C instantly. Moreover, MoSe2爓as synthesized between high-valent molybdeunm halide and alkali-metal selenide in organic solvents?ct[12]. In other studies, Zhan prepared MoSe2爓ith a solv