化学前沿2——核壳结构材料入门.ppt

TEM photographs of SiO2@polystyreneusing different SLS concentrations The size and morphology of nanocomposite particles could be tuned by adjusting the silica particle size and surfactant concentration. the size of the nanocomposite particles decreased with increasing surfactant concentration Langmuir 2005, 21, 2124-2128 40 mM 30 mM Ag@Polymer via Miniemulsion Polymerization TEM images of silver particles: (A) uncoated particle, (B) polystyrene/methacrylate coated particles, (C) polystyrene/methacrylate coated particles with a covalently bound BSA layer, and (D) the same as panel C after exposure to gold colloids. J. Am. Chem. Soc. 1999, 121, 10642-10643 Extinction spectra of silver particles: (A) uncoated particles and (B) polystyrene coated particles. Solid line: suspension in water. Dotted line: suspension in water, after 1 h in 1.8 M NaCl. Polymer-Coated Functionalized Silver Nanoparticles J. Am. Chem. Soc. 1999, 121, 10642-10643 Fabrication of AgCl@Polypyrrole-Chitosan Core-Shell Nanoparticles Langmuir, Vol. 20, No. 23, 2004 9911 TEM images of (b)AgCl@PPy-CS nanoparticles, and (c) PPy-CS hollow nanospheres.Reaction conditions: 20 mL of chitosan (1 wt %, in0.05 M HNO3), 0.01 g of AgNO3, 0.025 mL of pyrrole, and 0.14g of FeCl3. The reaction temperature is 2 ℃. Fabrication of AgCl@Polypyrrole-Chitosan Core-Shell Nanoparticles Langmuir, Vol. 20, No. 23, 2004 9911 Fabrication of AgCl@Polypyrrole-Chitosan Core-Shell Nanoparticles Langmuir, Vol. 20, No. 23, 2004 9911 UV-vis absorption spectra XRD patterns Metal@Polymerby Miniemulsion Polymerization：multi-core Journal of Polymer Science, 48, 1594–1606 (2010) Miniemulsion Polymerization and Thiol-ene Functionalization process incorporation of multiple metal domains into a single polymeric particle Representative transmission electron micrograph from synthesis of composite polymer–gold nanoparticles using oleylamine-stabilized gold nanoparticles. Inset at top right shows both gold nanoparticle aggregation and incom