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DMPA含量对不同软段结构水性聚氨酯性能的影响.pdf
2015年9月第24卷第 9期 中 国胶 粘 剂
Vo1.24No.9,Sep.2015 CHINAADHESIVES (504 )一23一
DMPA含量对不同软段结构水性聚氨酯性能的影响
罗晓民,葛炳辉 ,冯见艳,杨菲菲
(陕西科技大学资源与环境学院,陕西 西安 710021)
摘 要:以聚酯多元醇、异佛尔酮二异氰酸酯(IPDI)和二羟甲基丙酸(DMPA)为主要原料,采用预聚体
分散法合成了一系列具有不同软段结构的水性聚氨酯(wPu)。研究结果表明:随着DMPA掺量的不断增加,
WPU的稳定性提高、黏度增大、粒径减小且粒径分布变窄 ,WPU胶膜的拉伸强度在一定范围内增大、断裂伸
长率降低、水接触角减小和耐水性下降,并且软段微区的结晶性能降低。
关键词:水性聚氨酯 ;二羟甲基丙酸;聚酯多元醇
中图分类号 :TQ433.432 文献标志码:A 文章编号:1004—2849(2015)09—0023—06
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