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《TYPES OF CHEMICAL BONDING》.pdf
1
TYPES OF CHEMICAL BONDING
Ionic Bonding
- Bond between ions whose charges attract each other
- One atom gives electrons and one atom takes electrons.
Example
Na+ Cl-
ionic bond
Covalent Bonding
- two atoms each sharing electrons within a molecular orbital
F – F
covalent bond
- both fluorine atoms “own” electrons within bond
OCTET RULE – Generally atoms prefer electron configurations with 8 valence electrons.
- Filled s and p subshells
Atoms bond with each other so that every atom has 8 electrons in its outer shell.
- Atoms may take electrons from each other or they may share electrons.
Octet rule is able to explain a lot of chemistry. I. e., it is able to explain why certain
elements combine together in specific proportions.
Exceptions to the octet rule are plentiful. We will consider these later.
2
LEWIS STRUCTURES
Only valence electrons are important in bonding.
Lewis dot structures show valence electrons surrounding atom.
We visualize the four valence orbitals of an atom as the sides of a box. Electrons are put
into orbitals according to Hund’s rule.
Examples
Be has 2 valence electrons.
Therefore Lewis structure is Be
N has 5 valence electrons.
N
Therefore Lewis structure is
Br has 7 valence electrons.
Br
Therefore Lewis structure is
C has 4 valence electrons.
C
Therefore Lewis structure is
IONIC BONDING (again)
- Oppositely charged ions attract
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