由生物质造气废液制环保型融雪剂的工艺方法研究.pdfVIP

由生物质造气废液制环保型融雪剂的工艺方法研究 1 1 1 2 1 1 1 1 许英梅 ,张树彪 ,姜慧明 ，张秋民 ，韩双 ，周威 ，段丽娟 ，魏艳红 1. 2. （大连民族学院，大连116600； 大连理工大学化工学院，大连 116012） 摘要：本论文利用当地生物质（麦秸杆、木屑等）气化转化过程中的醋酸废液-木醋液（黑 褐色）与价格低廉的白云石粉等为原料，通过转化、脱色、蒸发结晶等过程，制备出近乎白 色的低成本环保型融雪剂（无腐蚀、融雪温度低）并可应用于工业生产。同时用分光光度法 系统研究了用活性炭进行吸附脱色的动力学模型，其吸附平衡方程为 C = 1.4863 - 0.8112t 2 3 + 0.1902t - 0.0144t 。这将为实现工业化在技术上提供理论根据，不仅是一个变废为宝， 为我国冬季道路除雪提供的一个绿色经济的有效办法，而且对生物质资源的可持续发展有现 实意义。 关键词：木醋液；环保型融雪剂；吸附脱色动力学 The study of technical method of making environmental thawing reagent from biological waste Yingmei Xu, Shubiao Zhang, Huiming Jiang, Qiumin Zhang, Shuang Han, Wei Zhou, Lijuan Duan, Yanhong Wei Abstract: In the paper, white cheap environmental thawing reagent is produced and applied in industry. Acetic acid waste- pyracetic acid (black) and cheap dolomite are used as starting materials, after a series of process such as transferring, decolorization, distillation and crystallization, our product is produced. Systematic study of dynamic model of absorption and decolorization by active carbon is carried out. The adsorption equilibrium equation is C = 1.4863 2 3 - 0.8112t + 0.1902t - 0.0144t which provides the theoretical foundation for its industrialization. It’s not only an environmental and economical method for thawing in winter in China, but is practically meaningful for the consecutive development of biological resources. Keywords: pyracetic acid, environmental thawing reagent, adsorption and decolorization dynamics 引言 在利用废木屑等木材加工残余物和麦秸杆等农业残余物（可再生的生物质）气化热解（干 馏）过程中产生大量的废液，俗称木醋液，颜色较深（黑褐色），其醋酸含量可达6%-12%， [1-4] 另外还含有少量的丙酸，甲酸，苯酚，焦油等 。由于生物质能消耗不会导致CO 排放